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About the group

Sustainability is a central evolving theme in the use of polymeric materials. Going from recycling of plastics, to the use of polymer membranes in separation processes (e.g., removing CO2 from air, purifying water) it is evident that polymer science has to evolve to answering these pressing questions of our time. We propose to addresses these societally critical questions by using the tools of fundamental science (including experiments, theory, simulations and the evolving tools of data science) to impact applications on a short time scales.

Our group employs a bottom-up approach to study these materials with a goal towards addressing the polymer waste problem (including polymer recycling/upcycling) and the formation/mitigation of nano plastics, which are thought to have significant health issues. We also work on developing better membranes, based on a polymer grafted nanoparticle construct, with improved gas separation abilities. In collaboration with others we focus on modeling the assembly of materials using DNA (with Oleg Gang) and modeling Biomolecular condensates (with Kyle Bishop). While our focus seems diverse, we are always guided by applications and by the need to establish their fundamental underpinnings. We combine experiments, simulations, theory and the new tools of data science to understand the driving forces that governs the behavior of these complex systems across scales.

News

Title: Nanoparticle Diffusion in Miscible Polymer Nanocomposite Melts

Abstract: X-ray photon correlation spectroscopy measurements were used to quantify the dynamics of bare and bimodal grafted silica nanoparticles mixed with PEO melts of different molecular weights. In dilute polymer nanocomposite (PNC) samples, we find diffusive NP behavior as described by the Stokes–Einstein relationship so long as the adsorbed PEO polymer layer is taken into account in determining both the effective NP size and its role on composite viscosity. The size of this bound layer was found to be approximately…

The lab is hosting Prof. Srikanth Sastry from Jawaharlal Nehru Centre for Advanced Scientific Research and Prof. Tarak Kumar Patra from IIT Madras for the summers. Welcome Prof. Sastry and Prof. Patra.